Heterogeneous catalytic activity on Mn, Fe and Co-based metalloporphyrinic Solid Coordination Frameworks (SCFs)

by / Thursday, 13 July 2017 / Published in

Heterogeneous catalytic activity on Mn, Fe and Co-based metalloporphyrinic Solid Coordination Frameworks (SCFs)


Published in: 1st European Conference on Metal Organic Frameworks and Porous Polymers,
2015/10/11
Publisher URL:
Authors:
Arkaitz Fidalgo-Marijuan Gotzone Barandika Begoña Bazán Miren-Karmele Urtiaga Edurne S. Larrea Marta Iglesias María Isabel Arriortua
Abstract:

Solid Coordination Frameworks (SCFs) have been widely explored on different catalytic reactions,and during the past years metalloporphyrins have been envestigating in order to mimick their natural activity in the solid state.2

Herein we present the catalytic activity results towards the oxidation reactions of different alcohols for MnTPPS, FeTCPP nad CoTPPS based metalloporphyrinc SCFs (TPPS= meso-tetrasulfonatophenylporphyrin, TCPP= meso-tetracarboxyphenylporphyrin).3 Additionally, Knoevenagel condensations and a ” one-pot ” reaction involving the FeTCPP based SCF catalyst have been carried out.

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